Publications

      

     

     

     

JOURNAL ARTICLES

2021

Hua, T., Ahmad, M., Choezin, T., and Hartman, R.L. “Microbe-Worm Symbiosis Stabilizes Methane Hydrates in Deep Marine Environments” (in review).

Wells, J., Chen, W., Hartman, R.L. and Koh, C. “Carbon dioxide hydrate in a microfluidic device: phase boundary and crystallization kinetics measurements with micro-Raman spectroscopy” (in review).

Liu, Y., Sabio, J.C., and Hartman, R.L. “A Counter-Current Flow Micro-Packed-bed DBD Plasmatron for the Synthesis of a Methylated Cobaloxime”, J. Phys. D: Appl. Phys., 54, 194003 (2021).

Cellini, F., Lavini, F., Chen, E., Bongiorno, A., Popovic, F., Hartman, R.L., Dingreville, R., and Riedo, E. “Pressure-induced formation and mechanical properties of 2D diamond boron nitride”, Adv. Sci., 8(2), 2002541 (2021).

2020

Hua, T., Valentín-Valentín, C., Gowayed, O., Lee, S., Garetz, B.A., and Hartman, R.L. “Microfluidic Laser-Induced Nucleation of Supersaturated Aqueous Glycine Solutions”, Cryst. Growth Des., 20, 10, 6502–6509 (2020).

Ho, D., Shkolnik, A.S., Ferraro, N.J., Rizkin, B.A., and Hartman, R.L. “Using Word Embeddings in Abstracts to Accelerate Metallocene Catalysis Polymerization Research”, Comput. Chem. Eng., 141(4), 107026 (2020).

Rizkin, B.A., and Hartman, R.L. “Activation of Homogenous Polyolefin Catalysis with a Machine-Assisted Reactor Laboratory-in-a-Box (μAIR-LAB)”, React. Chem. Eng., 5, 1450-1460 (2020).

Morais, S., Cario, A., Liu, N., Bernard, D., Lecoutre, C., Garrabos, Y., Ranchou-Peyruse, A., Dupraz, S., Azaroual, M., Hartman, R.L., and Marre, S. “Studying key processes related to CO₂ underground storage at the pore scale using high pressure micromodels”, React. Chem. Eng., 5, 1156-1185 (2020).

Hartman, R.L. “Flow Chemistry Remains an Opportunity for Chemists and Chemical Engineers”, Curr. Opin. Chem. Eng., 29, 1-9 (2020).

Rizkin, B.A., Shkolnik, A.S., Ferraro, N.J., and Hartman, R.L. “Combining automated microfluidic experimentation with machine learning for efficient polymerization design”, Nat. Mach. Intell., 2, 200-209 (2020).

2019

Rizkin, B.A., and Hartman, R.L. “Supervised Machine Learning for Prediction of Zirconocene-Catalyzed alpha-Olefin Polymerization”, Chem. Eng. Sci., 210, 115224 (2019).

Chen, W., Guo, T., Kapoor, Y., Russel, C., Juyal, P., Yen, A., and Hartman, R.L. “An Automated Microfluidic System for the Investigation of Asphaltenes Deposition and Dissolution in Porous Media”, Lab Chip, 19, 3628-3640 (2019). [Featured on the Back Cover].

Rizkin, B.A., Popovic, F., and Hartman, R.L. “Spectroscopic microreactors for heterogeneous catalysis”, J. Vac. Sci. Technol. A, 37, 050801 (2019). [Cover]

Liu, Y., and Hartman, R.L. “Reaction kinetics of a water-soluble palladium-beta-cyclodextrin catalyst for a Suzuki-Miyaura cross-coupling in continuous-flow”, React. Chem. Eng., 4, 1341-1346 (2019).

Hua, T., Gowayed, O., Grey-Stewart, D., Garetz, B.A., and Hartman, R.L. “Microfluidic Laser-Induced Nucleation of Supersaturated Aqueous KCl Solutions”, Cryst. Growth Des., 19(6), 3491-3497 (2019).

Hua, T. and Hartman, R.L. “Computational Fluid Dynamics of DNA Origami Folding in Microfluidics”, React. Chem. Eng., 4, 818-827 (2019).

Rizkin, B.A., Popovich, K., and Hartman, R.L. “Artificial Neural Network Control of Thermoelectrically-Cooled Microfluidics using Computer Vision based on IR Thermography”, Comput. Chem. Eng., 121(2), 584-593 (2019).

2018

Chen, W. and Hartman, R.L. “Methane hydrate intrinsic dissociation kinetics measured in a microfluidic system by means of in-situ Raman spectroscopy” Energy Fuel, 32(11), 11761-11771 (2018). [Featured on a Supplementary Cover]

Chen, W., Vashistha, P., Yen, A., Joshi, N., Kapoor, Y., and Hartman, R.L. “Asphaltenes dissolution mechanism study by in-situ Raman characterization of a packed-bed microreactor with HZSM-5 aluminosilicates” Energy Fuel, 32(12), 12205-12217 (2018). [Featured on a Supplementary Cover]

Rizkin, B.A. and Hartman, R.L. “Catalytic activity of Pd/hydrophilic phosphine ligand in the interface of an aqueous-phase Cu-free Sonogashira coupling”, React. Chem. Eng., 3, 251-257 (2018). [Featured on the Inside Front Cover].

2017

Pinho, B., Liu, Y., Rizkin, B., and Hartman, R.L. “Confined methane-water interfacial layers and thickness measurements using in situ Raman spectroscopy”. Lab Chip, 17, 3883-3890 (2017).

Pinho, B., Minsariya, K., Joshi, N., Yen, A., and Hartman, R.L. “Role of HZSM-5 Aluminosilicates on Asphaltenes Deposition by High-throughput in Situ Characterizations of a Microreservoir”. Energy Fuel, 31(11), 11640-11650 (2017).

Chen, W., Pinho, B., and Hartman, R.L. “Flash crystallization kinetics of methane (sI) hydrate in a thermoelectrically-cooled microreactor”, Lab Chip, 17, 3051-3060 (2017) [Featured on the Inside Front Cover].

Pinho, B. and Hartman, R.L. “Microfluidics with in situ Raman spectroscopy for the characterization of non-polar/aqueous interfaces”, React. Chem. Eng., 2, 189 (2017) [For the Invited Emerging Investigators Issue].

2016

Pinho, B. and Hartman, R.L. “Microfluidics with in situ Raman spectroscopy for the characterization of non-polar/aqueous interfaces”, React. Chem. Eng., (2016), DOI: 10.1039/c6re00177g.

Hu, C., Yen, A., Joshi, N., and Hartman, R.L. “Packed-bed Microreactors for Understanding of the Dissolution Kinetics and Mechanisms of Asphaltenes in Xylenes”, Chem. Eng. Sci., 140, 144-152 (2016).

Hu, C., Shaughnessy, K.H., and Hartman, R.L. “Influence of water on the deprotonation and the ionic mechanisms of a Heck alkynylation and its resultant E-factors”, React. Chem. Eng., 1, 65-72 (2016).

Hu, C., Garcia, N., Xu, R., Cao, T., Yen, A., Garner, S., Macias, J., Joshi, N., and Hartman, R.L. “Interfacial Properties of Asphaltenes at the Heptol-Brine Interface”, Energ. Fuel., 30 (1), 80-87 (2016).

2015

Sabio, J.C., Domier, R.C., Moore, J.N., Shaughnessy, K., and Hartman, R.L. “Palladium theory of aqueous-phase Heck alkynylations for intensification of discovery and manufacture”, Chem. Eng. Technol., 38, 1717-1725 (2015).

Chen, Y., Sabio, J.C., and Hartman, R.L. “When solids stop flow chemistry in commercial tubing”, J. Flow Chem., 5(3), 166-171 (2015).

2014

Hu, C., Sabio, J.C., and Hartman, R.L. “Role of water on the precipitation and deposition of asphaltenes in packed-bed microreactors”, Ind. Eng. Chem. Res., 54 (16), 4103-4112 (2014).

Hu, C. and Hartman, R.L. “High-throughput packed-bed microreactors with inline analytics for the discovery of asphaltene deposition mechanisms”, AIChE J., 60, 3534-3546 (2014).

Hu, C., Morris, J.E., and Hartman, R.L. “Microfluidic investigation of the deposition of asphaltenes in porous media”, Lab Chip, 14, 2014-2022 (2014).

Domier, R.C. and Hartman, R.L. “Chemical reaction engineering perspectives on the role of water in fine chemicals and pharmaceuticals manufacture”, Chim. Oggi.-Chem. Today, 32 (4), 17-21 (2014).

2013

Hu, C, Herz, C., and Hartman, R.L. “Microfluidic dispersion of mineral oil-seawater multiphase flows in the presence of dialkyl sulfonates, polysorbates, and glycols”, Green Process Synth., 2, 611-623 (2013).

Domier, R.C., Moore, J.N., Shaughnessy, K., and Hartman, R.L. “Kinetic analysis of aqueous- phase Pd-catalyzed, Cu-free direct arylation of terminal alkynes using a hydrophilic ligand”, Org. Process Res. Dev., 17 (10), 1262-1271 (2013).

2012

Flowers, B.S. and Hartman, R.L. “Particle handling techniques in microchemical systems”, Challenges, 3, 194-211 (2012).

Hartman, R.L. “Managing solids in the upstream continuous processing of fine chemicals”, Org. Process Res. Dev., 16, 870-887 (2012).

2011

Hartman, R.L., McMullen, J.P. and Jensen, K.F. “Deciding whether to go with the flow – evaluating the merits of flow reactors for synthesis”, Angew. Chem. Int. Ed., 40, 2-20 (2011).

Noel, T., Naber, J.R., Hartman, R.L., McMullen, J.P., Jensen, K.F. and Buchwald, S.L. “Palladium-catalyzed amination reactions in flow: overcoming the challenges of clogging via acoustic irradiation” Chem. Sci., 2, 287-290 (2011).

Kuhn, S., Hartman, R.L., Sultana, M., Nagy, K.D., Marre, S. and Jensen, K.F. “Teflon-coated silicon microreactors: impact on segmented liquid-liquid multiphase flows”, Langmuir, 27, 6519-6527 (2011).

2010

Hartman, R.L., Naber, J.R., Zaborenko, N. Buchwald, S.L. and Jensen, K.F. “Overcoming the challenges of solid bridging and constriction during Pd-catalyzed C-N bond formation in microreactors”, Org. Process Res. Dev., 14, 1347-1357 (2010).

Hartman, R.L., Naber, J.R., Buchwald, S.L. and Jensen, K.F. “Multi-step microchemical synthesis enabled by microfluidic distillation”, Angew. Chem. Int. Ed., 49, 899-903 (2010).

2009

Hartman, R.L. and Jensen, K.F. “Microchemical systems for continuous-flow synthesis”, Lab Chip, 9, 2495-2507 (2009).

Hartman, R.L., Sahoo, H.R., Yen, B.C. and Jensen, K.F. “Distillation in microchemical systems using capillary forces and segmented flow”, Lab Chip, 9, 1843-1849 (2009).

2005-2008

Hartman, R.L. and Fogler, H.S. “Understanding the dissolution of zeolites”, Langmuir, 23, 5477-5484 (2007).

Hartman, R.L. and Fogler, H.S. “The unique mechanism of analcime dissolution by hydrogen ion attack”, Langmuir, 22, 11163-11170 (2006).

Hartman, R.L., Lecerf, B., Frenier, W., Ziauddin, M. and Fogler, H.S. “Acid-sensitive aluminosilicates: dissolution kinetics and fluid selection for matrix stimulation treatments”, SPE Prod. Oper., 21, 194-204 (2006).

Hartman, R.L. and Fogler, H.S. “Reaction kinetics and mechanisms of zeolite dissolution in hydrochloric acid”, Ind. Eng. Chem. Res., 44, 7738-7745 (2005).

 

BOOKS

Wolf, N. and Hartman, R.L. (editors), “Formation, Removal, and Inhibition of Inorganic Scale in the Oilfield Environment” by W. Frenier and M. Ziauddin, Society of Petroleum Engineers, 2008, 230 pp.

 

U.S. PATENTS

2018

Hartman, R.L., Panga, M.K.R., Drochon, B., Still, J.W., Abad, C., Garcia-Lopez De Victoria, M., England, K.W., and Aviles, I. “Methods to deliver fluids on a well site with variable solids concentration from solid slurries”, Schlumberger Technology Corporation, US 10,011,763 (2018).

2016

Panga, M.K.R., Sullivan, P.F., Gadiyar, B., Hartman, R.L., Drochon, B., Still, J.W. and Stamm, B. “High Solids Content Slurries and Methods”, Schlumberger Technology Corporation, US 9,238,772 (2016).

2014

Fuller, M.J., Couillet, I. and Hartman, R.L. “Method of Treating Sandstone Formations with Reduced Precipitation of Silica”, Schlumberger Technology Corporation, US 8,802,601 (2014).

Panga, M.K.R., Sullivan, P.F., Gadiyar, B., Hartman, R.L., Drochon, B., Still, J.W. and Stamm, B. “High solids content slurries and methods”, Schlumberger Technology Corporation, US 8,765,646 (2014).

Hartman, R.L., Naber, J.R., Zaborenko, N., McMullen, J.P. and Jensen, K.F. “Methods for handling solids in microfluidic systems”, Massachusetts Institute of Technology, US 8,763,623 (2014).

Hartman, R.L., Panga, M.K.R., Drochon, B. and Still, J.W. “System and Method for Low Damage Fracturing”, Schlumberger Technology Corporation, US 8,752,627 (2014).

2013

Hartman, R.L., Panga, M.K.R., Drochon, B. and Still, J.W. “System and Method for Low Damage Fracturing”, Schlumberger Technology Corporation, US 8,496,056 (2013).

Panga, M.K.R., Photos, P.J., Drochon, B., Still, J.W., Gadiyar, B., Hartman, R.L., and Stamm, B. “High Solids Content Slurries and Methods”, Schlumberger Technology Corporation, US 8,490,698 (2013).

Hartman, R.L., Sahoo, H. and Jensen, K.F. “Small-Scale Method and Apparatus for Separating Liquid Mixtures”, Massachusetts Institute of Technology, US 8,435,387 (2013).

2012

Panga, M.K.R., Gadiyar, B., Hartman, R.L., Drochon, B., Still, J.W., and Stamm, B. “System and method for low damage gravel packing”, Schlumberger Technology Corporation, US 8,210,249 (2012).

Panga, M.K.R., Sullivan, P.F., Gadiyar, B., Hartman, R.L., Drochon, B., Still, J.W. and Stamm, B. “High Solids Content Slurries and Methods”, Schlumberger Technology Corporation, US 8,119,574 (2012).

2010-2011

Panga, M.K.R., Gadiyar, B., Hartman, R.L., Drochon, B., Still, J.W. and Stamm, B. “Method and composition comprising at least three different average particle volume particulates for low damage gravel packing”, Schlumberger Technology Corporation, US 8,008,234 (2011).

Panga, M.K.R., Gadiyar, B., Hartman, R.L., Drochon, B., Still, J.W. and Stamm, B. “System and Method for Low Damage Gravel Packing”, Schlumberger Technology Corporation, US 7,789,146 (2010).

Hartman, R.L., Panga, M.K.R., Drochon, B. and Still, J.W. “System and Method for Low Damage Fracturing”, Schlumberger Technology Corporation, US 7,784,541 (2010).

 

U.S. PATENT APPLICATIONS

2019

Hartman, R.L., Garetz, B., Hua, T., and Gowayed, O. “Systems and Methods for Continuous-Flow Laser-Induced Nucleation”, New York University, US 62/877,670 (2019).

Hartman, R.L. and Rizkin, B.A. “Method and Apparatus for the Rapid Discovery and Design of Polymerizations”, New York University, US 62/892,453 (2019).

2012-2015

Hartman, R.L. and Flowers, B.S. “Methods and Apparatuses for Producing Clathrate Hydrates”, New York University, US 20150008367 (2015).

Hartman, R.L., Panga, M.K.R., Drochon, B., Still, J.W., Abad, C., Garcia-Lopez De Victoria, M., England, K.W., and Aviles, I. “Methods to Deliver Fluids on a Well Site with Variable Solids Concentration from Solid Slurries”, Schlumberger Technology Corporation, US 20140069645 (2014).

Hartman, R.L., Panga, M.K.R., Drochon, B. and Still, J.W. “System and Method for Low Damage Fracturing”, Schlumberger Technology Corporation, US 20130264055 (2013).

Panga, M.K.R., Sullivan, P.F., Gadiyar, B., Hartman, R.L., Drochon, B., Still, J.W. and Stamm, B. “High Solids Content Slurries and Methods”, Schlumberger Technology Corporation, US 20120138296 (2012).

2011

Panga, M.K.R., Gadiyar, B., Hartman, R.L., Drochon, B., Still, J.W. and Stamm, B. “System and Method for Low Damage Gravel Packing”, Schlumberger Technology Corporation, US 20110265985 (2011).

Panga, M.K.R., Sullivan, P.F., Gadiyar, B., Hartman, R.L., Drochon, B., Still, J.W. and Stamm, B. “High Solids Content Slurries and Methods”, Schlumberger Technology Corporation, US 20110155371 (2011).

Hartman, R.L., Naber, J.R., Zaborenko, N., McMullen, J.P. and Jensen, K.F. “Systems and Methods for Handling Solids in Microfluidic Systems”, Massachusetts Institute of Technology, US 20110126914 (2011).

Hartman, R.L., Panga, M.K.R., Drochon, B. and Still, J.W. “System and Method for Low Damage Fracturing”, Schlumberger Technology Corporation, US 20110005760 (2011).

2010

Panga, M.K.R., Sullivan, P.F., Gadiyar, B., Hartman, R.L., Drochon, B., Still, J.W. and Stamm, B. “High Solids Content Methods and Slurries”, Schlumberger Technology Corporation, US 20100300688 (2010).

Panga, M.K.R., Gadiyar, B., Hartman, R.L., Drochon, B., Still, J.W. and Stamm, B. “System and Method for Low Damage Gravel Packing”, Schlumberger Technology Corporation, US 20100243250 (2010).

Boney, C.L., Dessinges, M.N., Drochon, B., Williamson, D., Sullivan, P.F., Auzerais, F.M., Still, J.W., Kubala, G., Mackay, B.A., Hartman, R.L., Couillet, I., Boyd, A. and Shampine, R. “Method for Completing Tight Oil and Gas Reservoirs”, Schlumberger Technology Corporation, US 20100243242 (2010).

Hartman, R.L., Sahoo, H. and Jensen, K.F. “Small-Scale Method and Apparatus for Separating Liquid Mixtures”, Massachusetts Institute of Technology, US 20100122899 (2010).

2008-2009

Fuller, M.J., Couillet, I. and Hartman, R.L. “Method of Treating Sandstone Formations with Reduced Precipitation of Silica”, Schlumberger Technology Corporation, US 20090233819 (2009).

Hartman, R.L., Panga, M.K.R., Drochon, B. and Still, J.W. “System and Method for Low Damage Fracturing”, Schlumberger Technology Corporation, US 20090025934 (2009).

Panga, M.K.R., Gadiyar, B., Hartman, R.L., Drochon, B., Still, J.W. and Stamm, B. “System and Method for Low Damage Gravel Packing”, Schlumberger Technology Corporation, US 20090025932 (2009).

Still, J.W., Couillet, I., MacKay, B.A. and Hartman, R.L. “Method of Heterogeneous Etching of Sandstone Formations”, Schlumberger Technology Corporation, US 20080314594 (2008).